|
Material Database:
Tributyl(trimethylsilyl)stannane
| |
|
| Producer |
Fluka Chemie GmbH
|
| Status |
Available |
| Material |
Liquid |
| Reference |
92781 |
| Catalog (Web) |
http://www.sigmaaldrich.com/catalog/search/ProductDetail/F
LUKA/92781 |
| |
|
Description
|
purum, ≥97.0% (GC) Synonym (Tributylstannyl)trimethylsilane
(Trimethylsilyl)tributylstannane (Trimethylsilyl)tributyltin
Molecular Formula [CH3(CH2)3]3SnSi(CH3)3
Molecular Weight 363.24
Other Notes Reagent undergoing cis-addition to terminal acetylenes with tin at the internal position1 ; Generation of tributylstannyl anions2
n20/D 1.488 (lit.) 1.488
bp 102-103 °C0.5 mm Hg (lit.)
density 1.04 g/mL at 25 °C (lit.)
Hazard Codes T,N
F 10-21 References: Fieser 17,364
FT-NMR 1 (3), 751:A / RegBook 1 (2), 3073:D / Structure Index 1, 487:A:7
Cited References: 1. B.L. Chenard, C.M. von Zyl J. Org. Chem. 51, 3561, (1986)
|
|
