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Material Database:
O-Phenyl chlorothionoformate
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| Producer |
SUPELCO by Sigma-Aldrich
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| Status |
Available |
| Material |
Liquid |
| Reference |
234524 |
| Catalog (Web) |
http://www.sigmaaldrich.com/catalog/search/ProductDetail/A
LDRICH/234524 |
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Description
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99% Synonym Phenyl thionochloroformate
Molecular Formula ClC(S)OC6H5
Molecular Weight 172.63
Application Reagent for thionocarbonylation of unprotected thymine nucleosides.1 Forms phenoxythiocarbonyl esters of protected ribonucleosides which can be reduced by tributyltin hydride (Cat. No. 23,478-8) to deoxyribonucleosides.2
n20/D 1.581 (lit.)
bp 81-83 °C6 mm Hg (lit.)
Fp 179 °F
density 1.248 g/mL at 25 °C (lit.)
Hazard Codes C
VBF AIII
F 10-21 References: 1. Synlett., 221, (1993)
2. Can. J. Chem. 71, 186, (1993)
Beil. 6,III,609
Fieser 10,306 Aldrich MSDS 1, 1460:D / Corp MSDS 1 (2), 2767:C / RegBook 1 (2), 1985:B / Structure Index 1, 318:C:4
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Package |
1, 5 g in glass btl
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