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The establishment of EVISA is funded by the EU through the Fifth Framework Programme (G7RT- CT- 2002- 05112).
Supporters of EVISA includes:
Certified reference materials for mercury in marine animal tissues
Monomethylmercury compounds are of great concern, as these highly toxic compounds are formed biotically by microorganisms in sediment and algae in sea water and/or abiotically. Once it is formed, methylmercury is bioaccumulated and biomagnified in the aquatic food chains, thus resulting in exposure levels among fish-eating populations, often at levels exceeding what is regarded as a safe level.
It is therefore of primary interest to have samples from animal species within the food chain at different trophic level.
The main issues to be controlled during the analysis of biological tissues for the speciation analysis of mercury are:
quantitativeness of extraction of the species from the tissue
absence of artificial formation of methylmercury during the analytical procedure
control of contamination mainly for inorganic mercury
control of the derivatization yield
avoidance of ion-exchange and adsorption problems on GC column packing materials
CRMs play a major role in the development and validation of methods and for quality control. The following certified reference materials (CRMs) are available for the speciation of mercury species in marine animal tissues:
Supplier
Name
Material
Certificate
IRMM
ERM-CE464
Tuna fish muscle
Total mercury, methylmercury
IAEA
IAEA 407
Sea fish tissue
(Ag),Al, As, Br, Ca, Cd, Co, Cr, Cu, Fe, Hg, MeHg, K, Li, Mg, Mn, Na, Ni, Pb, Rb, Sb, Se, Sr, V, Zn
NIST
SRM 1566 b
Oyster tissue
Ca, Cl, Mg, K, Na, S, Al, As, Cd, Co, Cu, Fe, Pb, Mn, Hg, MeHg, Ni, Rb, Se, Ag, Th, V, Zn
NIST
SRM 1974 B
Mussel tissue
Hg, methylmercury, Organics
NIST
SRM 2976
Mussel tissue
As, Cd, Cu, Fe, Pb, Se, Zn, Total Hg, MeHg
NIST
SRM 2977
Mussel tissue
Cd, Cu, Pb, Mn, Ni, Sr, PAHs, PCBs, MeHg
NIST
SRM 1946
Freshwater fish
NRCC
DORM-2
Dogfish muscle
Al, As, Cd, Co, Cr, Cu, Fe, Pb, Mn, Hg, Ni, Se, Ag, Tl, Sn, Zn, MeHg
NRCC
DORM-3
Fish protein
As, Cd, Cu, Cr, Fe, Pb, Hg, Ni, Sn, Zn, MeHg
NRCC
DOLT-3
Dogfish liver
As, Cd, Cu, Fe, Pb, Hg, Ni, Se, Ag, (MeHg)
NRCC
DOLT-4
Dogfish liver
As, Cd, Cu, Fe, Pb, Hg, Ni, Se, Ag, Zn, MeHg
NRCC
LUTS-1
Non-defatted lobster tissue
As, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Ni, K, Se, Ag, Sr, Zn, [Hg], [MeHg]
NRCC
TORT-2
Lobster tissue
As, Cd, Co, Cr, Cu, Fe, Pb, Mn, Hg, Mo, Ni, Se, Sr, Sn, V, Zn, MeHg
* () =information value only, []= original certification no longer valid
NB:! click on the suppliers name to reach his website, click on the material name for a link to the report, click on the certified species for a link to the certificate
Related EVISA Resources
Material Database: Materials related to mercury speciation
Material Database: Mercury in sediments
Material Database: Mercury in soils
Material Database: Mercury in human tissues
Material Database: Mercury in animal tissue
Material Database: Mercury standards
Material Database: Mercury Isotopic Materials
Material Database: Materials for mercury speciation
Link Page: All about CRMs
Brief summary: Certified reference materials for mercury in marine animal tissues
Brief summary: Certified reference materials for mercury in biological materials
Brief summary: Certified Reference Materials for Speciation Analysis
back to the summary table
last time modified: July 22, 2008
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